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Comprehensive Guide to Laundry Detergent Formulation and Surfactant Selection

Views: 1564     Author: Site Editor     Publish Time: 2026-01-21      Origin: Site

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Industry Overview and Trends

Laundry detergents are precision-engineered products designed for specific cleaning needs. The market is shifting from traditional powders to liquid detergents. Unlike powders, which can leave residues and damage fabrics, liquid detergents offer rapid solubility and excellent low-temperature stability. Their mildness and high biocompatibility make them the preferred choice for modern consumers.

Core Performance Indicators

Developing a successful laundry detergent requires balancing cleaning power, sensory experience, and fabric protection.

1. Primary Detergency

Primary detergency measures the immediate ability of a detergent to remove stains and restore whiteness during the first wash.

  • Mechanism: This is achieved through the synergistic effect of surfactants. They lower surface tension to peel, emulsify, and solubilize dirt.

  • Optimization: Incorporating biological enzymes (protease, lipase) and builders targets stubborn protein and grease-based stains.

Washing-clothes-in-a-washing-machine-(scene)

2. Secondary Detergency

Secondary detergency determines the fabric's condition after cyclic washing (multiple wash cycles).

  • Anti-redeposition: The formula must prevent removed oil and inorganic soaps from re-attaching to the fabric.

  • Fiber Protection: Poor secondary detergency leads to "graying" and fabric hardening. This accumulation of soil shortens the lifespan of the garment and dulls its color.

3. Foam Control and Rinsing

While foam helps suspend soil, excessive suds can overflow machines and waste water.

  • Solutions: Formulators use low-foam surfactants, fatty acid soaps, or high-performance silicone defoamers. It is crucial to ensure these components remain stable and transparent within the system.

4. High Added Value

Modern detergents are evolving with specialized functions:

  • Multi-functional: Features include antibacterial properties, fabric softening, anti-static, and color protection.

  • Encapsulation: Fragrance microcapsule technology ensures long-lasting scent even after drying.

  • Sustainability: Trends favor concentrated formulas (lower carbon footprint) and biodegradable ingredients.

Key Ingredient Systems in Detergent Formulation

1. Surfactant System (Active Ingredients)

  • Anionic Surfactants: Provide core cleaning power and foam. Common choices include Sodium Lauryl Ether Sulfate (SLES/AES), Linear Alkylbenzene Sulfonate (LAS), and Alpha Olefin Sulfonate (AOS).

  • Non-ionic Surfactants: Offer superior emulsification and hard water resistance. Fatty alcohol ethoxylates (AEO-7, AEO-9) act as primary boosters.

  • Green Alternatives:Alkyl polyglycosides (APG) are increasingly used for their extreme mildness and ecological safety.

  • Standard: Industry standards recommend a total active matter content of at least 15%, with higher levels for concentrated products.

2. Bio-Enzyme System

Enzymes such as protease, lipase, cellulase, and amylase provide molecular-level stain removal. Cellulase specifically helps with color brightening and anti-pilling.

3. Anti-redeposition and Dispersant System

Polymers like Sodium Polyacrylate and PVP (Polyvinylpyrrolidone) are vital. PVP prevents "dye transfer," ensuring that colors do not bleed between different garments during the wash.

4. pH Regulation and Chelation System

  • Regulators: KOH, NaOH, or Triethanolamine (TEA) are used for neutralization.

  • Green Chelating Agents: Modern formulas swap EDTA for biodegradable alternatives like GLDA or MGDA. These sequester calcium and magnesium ions to prevent surfactant deactivation.

5. Rheology and Stability System

  • Viscosity: Sodium Chloride (NaCl) adjusts the thickness of AES-based systems.

  • Solvents: In concentrated formulas, Propylene Glycol or Sodium Xylenesulfonate (SXS) ensure the product remains clear and stable at low temperatures.

6. Preservation and Aesthetics

Preservatives like Kathon or Bronopol ensure biological stability. Fragrances and dyes provide a pleasant appearance and long-lasting scent.

Conclusion and Future Outlook

Laundry detergent research is a complex engineering task. The future lies in high concentration, water-saving technologies, and green chemistry. By integrating functional monomers—such as anti-pilling agents and fragrance capsules—manufacturers can meet the diverse, professional needs of today’s global consumers.



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